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Asta and Yuno were abandoned at the same church on the same day. Raised together as children, they came to know of the "Wizard King"—a title given to the strongest mage in the kingdom—and promised that they would compete against each other for the position of the next Wizard King. However, as they grew up, the stark difference between them became evident. While Yuno is able to wield magic with amazing power and control, Asta cannot use magic at all and desperately tries to awaken his powers by training physically. When they reach the age of 15, Yuno is bestowed a spectacular Grimoire with a four-leaf clover, while Asta receives nothing. However, soon after, Yuno is attacked by a person named Lebuty, whose main purpose is to obtain Yuno's Grimoire. Asta tries to fight Lebuty, but he is outmatched. Though without hope and on the brink of defeat, he finds the strength to continue when he hears Yuno's voice. Unleashing his inner emotions in a rage, Asta receives a five-leaf clover Grimoire, a "Black Clover" giving him enough power to defeat Lebuty. A few days later, the two friends head out into the world, both seeking the same goal—to become the Wizard King! [Written by MAL Rewrite]

Five years ago, alien beings known as the "Kiseichuu'' invaded the world. With the species endangered, the Kiseichuu are determined to take over Earth through a deadly plan that would gradually wipe out the human race: take away humanity's sexual drive using various methods, letting them die out. In response to the Kiseichuus' scheme, the HxEros device was developed—a powerful weapon that only those with high levels of erotic energy can utilize at its maximum capacity. Retto Enjou, a high schooler harboring an immense hatred toward the Kiseichuu, joins a group of HxEros users to fight against them and protect humankind. With their gear reliant on erotic energy as a source of power, the team must work together to maintain high levels of libido to ensure their readiness for combat at any given time. Moreover, as he lives in a house full of lustful girls, Enjou should not expect a shortage of power anytime soon. [Written by MAL Rewrite]

The story begins with the peaceful daily life of schoolgirls—which suddenly breaks down when former schoolmates become zombies. The story follows the actions taken by the girls left behind on the school roof. (Source: ANN) A short special edit of the OVA, titled Alice in Deadly School Tokubetsu-ban: Ima, Stage no Maku ga Agaru (Alice in Deadly School Special Edit -The Stage Begins-), was broadcasted on January 4, 2021 as part of the New Year's special.

Mini web anime streamed online leading up to the Mars Red TV anime premiere.