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Heavens Library to Crimson Lord brings back Arata, Lilith, and the rest of the Trinity Seven to face off against the greatest enemy in the history of the Trinity Seven; Lilith's own father, who is revealed to be the strongest Demon Lord, challenges Arata who is now a Demon Lord candidate. (Source: Avex Pictures, edited)

The film's story begins when Arata inadvertently touches "Hermes Apocrypha," Lilith's Grimoire. Suddenly, he is enveloped by a bright white light, and a girl appears before him. She calls herself Lilim, and treats both Arata and Lilith as her parents. At the same time she appears, something changes in the world. The forbidden Eternal Library awakens. In the Library is sealed the ultimate culmination of Alchemy, the White Demon Lord. The White Demon Lord plots to eliminate Arata and the Trinity Seven to usurp the position of Demon Lord. Bristling with untold power, the White Demon Lord attacks Arata, and triggers a desperate crisis where Arata and the Trinity Seven must save the world in this last battle. (Source: ANN)

One day, the bright red sun stopped shining, causing the "Breakdown Phenomenon"—the destruction of Arata Kasuga's town and the disappearance of the people inhabiting it. All, however, is not yet lost; by utilizing the magical grimoire given to him by his childhood friend and cousin Hijiri Kasuga, Arata's world gets artificially reconstructed. In order to investigate the phenomenon, Lilith Asami appears before Arata, whose artificial world suddenly disintegrates. He is given two choices: hand over the book, or die. However, Arata chooses the third option—enrolling in the top-secret magic school Royal Biblia Academy, where six other magical users await him. Together with Lilith, these six form the Trinity Seven, the elite of the school who each bolster their own power and skill. With the ambition to save Hijiri and the help of his newfound friends, Arata stops at nothing to prevent the destruction of his beloved hometown and to bring his best friend back. [Written by MAL Rewrite]

In a deadly terrorist attack, Arashi Mikami narrowly escapes death but loses everything in the process, including his family and best friend. However, the surgeon that rescues him is far from just an ordinary doctor—he commands a strike team known as Black Label whose task is to exterminate deadly criminals who have fallen too far. Filled with a new determination, Arashi joins the ranks of the vigilante organization. Black Label's targets are aplenty, as evil scum lurks everywhere—dangerous arms dealers, corrupt politicians, and shady gangsters all find themselves hunted by the extermination team. Although haunted by their dark and sinister past, all of the hunters are highly skilled at slaying their targets. In spite of the perilous lives the members live, Arashi and the gorgeous ladies surrounding him still manage to get caught up in a variety of sultry moments and racy hijinks. Though they face strong opposition, nothing can stop Black Label's objective of cleansing the world of ghastly evil. [Written by MAL Rewrite]